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More facts about N2O brain damage
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Newsgroups: alt.drugs
From: [email protected].org (Keith Lewis)
Subject: Re: Seeking facts about N2O brain damage.
Message-ID: <[email protected].org>
Date: Wed, 23 Jun 1993 17:25:48 GMT
In article <[email protected]>, [email protected] (Dale Clark) wres:
>CREATION PROCESS
>----------------
>Nitrous Oxide (laughing gas) is most commonly made by the thermal
>decomposition of ammonium nitrate (NH4NO3). The chief impurity
>of the product is N2, although, NO2, N, O2, and CO2 may also be present,
>however, usually not in any quantity to approach toxcity. The resulting
>mixture is passed through water for purification.
You left out NO (nitric oxide), NH3 (ammonia), and H2O (water -- the other
product of the *successful* reaction). _Laughing Gas_ also states that the
temperature (optimum or self-regulating, I don't know) for the reaction is
240 C. But they caution against trying it at home:
Occaionally, following in the footsteps of Priestly and Davy,
individuals attempt to synthesize N2O. This is definitely not
recommended, for several reasons. First, the synthetic process
frequently employed (heating ammonium nitrate) may lead to an explosion,
and has been the cause of major accidents and numerous injuries in the
industrial synthesis of N2O. Second, other oxides of nitrogen may be
obtained as byproducts of the synthetic process. One of these, nitrogen
diooxide, is extremely toxic, and can lead to rapid destruction of lung
tissue, even if inhaled in small quantities.
From what I read on rec.pyrotechnics, nitrogen dioxide lung damage is
permanant and cumulative.
_Laughing Gas_ also states that the boiling point of N2O is -88.44 C and
that the partial pressure at 27.4 C is 60 atm (!). Does that mean those
little whippits can withstand 60 atm??
I tend to think the danger of explosion is low if you keep the pressure
down. The "Dr. Atomic" cartoon instructions even go so far as to make it an
open system -- the end is a plastic bag LOOSELY HELD over the last hose. The
good doctor says that you should only synthesize it if you are a
professional chemist working under controlled laboratory conditions, but in
the picture there is a home setup using three flasks. The first one
contains the NH4NO3 and is heated. The third is a "bong" type device which
bubbles the gas through water. The second is a trap to prevent the "bong"
water from reaching the heated flask under negative pressure.
I wouldn't really worry about inhaling small quantities of ammonia, but I'd
like to figure out a way to neutralize the NO and NO2. Would they react
with baking soda (in the bubble flask)?
The PYRO file from rec.pyrotechnics lists two sources of ammonium nitrate.
One is fertilizer, the other is "instant cold packs". I wonder how pure
it is...
--Keith Lewis klewis@mitre.org "Mr. Cheap"
I don't dance to music; music dances to me. Email me for my PGP key.
The above may not (yet) represent the opinions of my employer.
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